• Product Name: Lithium Hexafluorophosphate
  • Short Name: LiPF6
  • Appearance: White crystal or powder
  • Purity: 99.9%
  • CAS No: 21324-40-3
  • HS Code: 2826909001
  • EINECS: 244-334-7

LiPF6, with the full name of Lithium hexafluorophosphate, is mainly used as an electrolyte material for lithium-ion batteries. LiPF6 electrolyte is usually mixed with organic solvents (such as dimethyl carbonate, ethylene carbonate, etc.) to form an electrolyte solution. Lithium hexafluorophosphate is a white crystalline powder that is easily soluble in water, low-concentration methanol, ethanol, acetone, carbonates and other organic solvents. It is the most commonly used electrolyte lithium salt in lithium-ion batteries and one of the main components of lithium battery electrolytes, especially in lithium-ion batteries. LiPF6 has strong cyclical properties and its price fluctuates greatly. If necessary, please feel free to contact us at any time, we are online 7X24 hours and will reply to you as soon as possible.

ItemLithium Hexafluorophosphate
Density1.50 g/cm3
Insoluble substance≤0.1%
Moisture≤20 ppm
Dissociation acid (HF)≤100ppm
Al≤5 ppm
Cu≤5 ppm
Cr≤5 ppm
Ca≤2 ppm
Fe≤5 ppm
Pb≤2 ppm
Mg≤5 ppm
Na≤5 ppm
Melting point200 °C
Molecular weight151.91 g/mol

Properties of Lithium Hexafluorophosphate LiPF6

‌Solubility and conductivity‌. Lithium hexafluorophosphate has a high solubility in organic solvents, especially in carbonate solvents such as dimethyl carbonate (DMC) and diethyl carbonate (DEC). It has a low degree of association and is easy to dissociate, which makes the ionic conductivity of the electrolyte higher. ‌ ‌

Electrochemical stability‌. LiPF6 has a wide electrochemical stability window, can remain stable at high voltage, and is not easy to react with electrode materials. In addition, it can form a stable solid electrolyte interface (SEI) film on the carbon negative electrode and effectively passivate the positive electrode aluminum foil to prevent its corrosion. ‌

‌Thermal stability and safety‌. Although lithium hexafluorophosphate has poor thermal stability and is easy to decompose at high temperatures, its comprehensive performance makes it still dominate in commercial applications. However, it is sensitive to water and will decompose to produce HF gas when it comes into contact with water, which may have an adverse effect on battery performance and service life. ‌

‌Environmental friendliness‌. Compared with other electrolytes, LiPF6 electrolyte has less environmental pollution and its decomposition products have a lower impact on the environment. ‌

Excellent Performance of LiPF6

  • Improve the ionic conductivity of the electrolyte. The main role of lithium hexafluorophosphate in the electrolyte is to increase the ionic conductivity. When it is dissolved in an organic solvent, a large number of lithium ions appear in the electrolyte, and these ions can move freely, thereby improving the conductivity of the electrolyte. This is crucial for the performance of lithium-ion batteries, because good conductivity is the basis for efficient battery operation.
  • Improve the energy density of the battery. Due to the addition of LiPF6, the concentration of lithium ions in the electrolyte increases, thereby increasing the energy density of the battery. Energy density is one of the important indicators for measuring battery performance, which determines the amount of electricity that the battery can store and release. Therefore, the use of lithium hexafluorophosphate helps to improve the endurance and performance of lithium-ion batteries.
  • Ensure the safety of the battery. In addition to improving performance, lithium hexafluorophosphate also helps to protect the safety of the battery due to its chemical and thermal stability. In high temperature environments, it is not easy to decompose and can maintain the stability of the electrolyte, thereby reducing the possibility of safety risks such as thermal runaway of the battery.

Main Applications of LiPF6 Electrolyte

LiPF6 powder is the most important component of the electrolyte. It is mainly used in lithium-ion power batteries, lithium-ion energy storage batteries and other daily batteries. It is also an irreplaceable lithium-ion battery electrolyte in the near and medium term. It provides strong support for the efficient and stable operation of lithium-ion batteries by improving the ionic conductivity of the electrolyte, increasing the energy density of the battery and ensuring the safety of the battery. With the continuous advancement of science and technology and the increasing maturity of battery technology, the application of lithium hexafluorophosphate LiPF6 will become more extensive, contributing to the development of electric vehicles, energy storage systems and other fields.

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